Polymerization and Synthesis from Biobased Feedstocks

聚合 聚合物 高分子科学 材料科学 单体 链生长聚合 石油化工 离子聚合 自由基聚合 化学 高分子化学 有机化学
作者
Michael Forrester,Fang‐Yi Lin,Eric W. Cochran
出处
期刊:Royal Society of Chemistry eBooks [The Royal Society of Chemistry]
卷期号:: 15-62
标识
DOI:10.1039/bk9781788010085-00015
摘要

There are a wide variety of methods for producing polymers derived from biological sources. As will be discussed in other chapters 8 and 9, it is possible to use natural polymers such as polysaccharides and proteins to produce biobased plastics directly. However, it is also possible to convert many types of biomass into monomers for polymerization into novel biopolymers. These materials may have unique properties that can make them preferred over their petrochemical analogues and as such are often referred to as “bioadvantaged polymers”. This chapter will review a select number of polymerization methods, their governing mechanisms, and basic theory for producing biobased plastics. In detail, step-growth polymerization, ionic polymerization, metathesis polymerization, and radical polymerization will be reviewed. In addition, some of the common challenges associated with these polymerization methods that arise from feedstocks that have a high degree of functionality, typical for biobased materials (plants based oils, proteins, and polysaccharides), will also be reviewed. These challenges can lead to low molecular weight polymers and/or broad molecular weight distributions. Thus, this chapter will review possible solutions to the challenges posed by the various polymerization methods.

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
大幅提高文件上传限制,最高150M (2024-4-1)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
有魅力勒发布了新的文献求助10
刚刚
刚刚
Lucas应助蓝愿采纳,获得10
2秒前
qazx完成签到,获得积分10
2秒前
3秒前
4秒前
今后应助激情的含巧采纳,获得10
5秒前
单薄天蓉完成签到,获得积分10
6秒前
7秒前
CodeCraft应助种桃老总采纳,获得10
7秒前
8秒前
8秒前
小胖发布了新的文献求助10
9秒前
王永俊完成签到 ,获得积分10
9秒前
11秒前
11秒前
11秒前
11秒前
科研通AI2S应助科研通管家采纳,获得20
11秒前
传奇3应助科研通管家采纳,获得10
11秒前
bkagyin应助科研通管家采纳,获得10
11秒前
乐乐应助科研通管家采纳,获得10
11秒前
科研通AI2S应助科研通管家采纳,获得10
11秒前
丸子圆圆应助科研通管家采纳,获得10
11秒前
小蘑菇应助科研通管家采纳,获得10
11秒前
orixero应助科研通管家采纳,获得10
11秒前
科研通AI2S应助科研通管家采纳,获得10
11秒前
Singularity应助科研通管家采纳,获得20
11秒前
小二郎应助科研通管家采纳,获得10
11秒前
科研通AI2S应助科研通管家采纳,获得10
11秒前
科研通AI2S应助科研通管家采纳,获得10
11秒前
12秒前
12秒前
Ztt完成签到,获得积分10
12秒前
橘子完成签到 ,获得积分10
13秒前
14秒前
小白发布了新的文献求助10
14秒前
蓝愿完成签到,获得积分10
15秒前
15秒前
淡定完成签到,获得积分20
15秒前
高分求助中
Evolution 10000
Sustainability in Tides Chemistry 2800
юрские динозавры восточного забайкалья 800
English Wealden Fossils 700
An Introduction to Geographical and Urban Economics: A Spiky World Book by Charles van Marrewijk, Harry Garretsen, and Steven Brakman 600
Diagnostic immunohistochemistry : theranostic and genomic applications 6th Edition 500
Mantiden: Faszinierende Lauerjäger Faszinierende Lauerjäger 400
热门求助领域 (近24小时)
化学 医学 生物 材料科学 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 基因 遗传学 催化作用 物理化学 免疫学 量子力学 细胞生物学
热门帖子
关注 科研通微信公众号,转发送积分 3153568
求助须知:如何正确求助?哪些是违规求助? 2804730
关于积分的说明 7861428
捐赠科研通 2462728
什么是DOI,文献DOI怎么找? 1310940
科研通“疑难数据库(出版商)”最低求助积分说明 629428
版权声明 601809