青色
荧光粉
材料科学
发光
显色指数
量子效率
发光二极管
热稳定性
晶体结构
二极管
光电子学
分析化学(期刊)
光学
结晶学
物理
化学
色谱法
量子力学
作者
Zhuihao Huang,Zeyu Lyu,Dashuai Sun,Sida Shen,Zheng Lu,Luhui Zhou,Shuai Wei,Hongpeng You
标识
DOI:10.1002/adom.202301172
摘要
Abstract Crystal‐field engineering can obtain targeted emission more effectively, compared with the laborious experimental screening of new hosts. However, there still lack of paradigms for obtaining Ce 3+ ‐doped cyan phosphors by crystal‐field engineering, and the correlation between the emission and the local structure of the Ce 3+ ions has rarely been disclosed. Herein, through substituting the K + in K 3‐y Rb y GdSi 2 O 7 :Ce 3+ with Rb + , the emission color changes from yellow‐green to cyan and finally to blue. In addition, the emission intensity and thermal stability greatly improve, as the internal quantum efficiency increases from 39.4% (y = 0) to 83.6% (y = 1.2), and the thermal activation energy increases from 0.25 eV (y = 0) to 0.36 eV (y = 1.2). The optimized luminescent properties have been interpretated from the change in energy level splitting and configuration coordinate of Ce 3+ , both of which originate from the elongated Ce 3+ ─O 2− bonds. Finally, the cyan‐emitting phosphor K 1.8 R 1.2 GSO:Ce 3+ is applied to bridge the cyan gap in a fabricated white light‐emitting diodes, and the color rendering index is improved from 90.8 to 93.4. This work not only provides an efficient cyan phosphor, but also highlights an avenue for the rational design of phosphors with optimal luminescent properties.
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