结构精修
结晶学
八面体
光致发光
分析化学(期刊)
晶体结构
荧光粉
兴奋剂
材料科学
离子
磷化物
X射线晶体学
光谱学
化学
衍射
物理
光学
金属
有机化学
冶金
量子力学
光电子学
色谱法
作者
Takahito Otsuka,Ryohei Oka,Tomokatsu Hayakawa
标识
DOI:10.1002/advs.202302559
摘要
In this study, Eu3+ and K+ co-doped Ca3 WO6 double perovskite, a high-color-purity red phosphor, is quantitatively investigated using synchrotron X-ray diffraction Rietveld refinement, energy dispersive X-ray spectroscopy, and high-resolution PL spectroscopy. The Eu3+ fluorescence line-narrowing (FLN) results, used to estimate the Eu3+ occupation at given sites (so-called A and B sites) in the host crystal (A2 BMO6 ; A, B = Ca; M = W), reveal that the Eu3+ ions have a twin distribution in both the A and B sites with high asymmetry ratios of ΛA = 9.7 and ΛB = 10.7, respectively. More interestingly, at lower Eu3+ doping levels, the ions are predominantly located at the B sites (≈75%), indicating that the high color purity of Ca3 WO6 :(Eu3+ , K+ ) is mainly caused by the high asymmetry ratios of the Eu3+ sites. Rietveld refinement combined with the FLN technique provides more reliable results for increasing the Eu3+ substitution at the A site with Eu3+ and K+ doping concentrations, which lower the lattice energy of Ca3 WO6 :(Eu3+ , K+ ). The structural distortions owing to K+ co-doping in terms of the quadratic elongation and bond-angle variance exhibit good correlations with the Ca(Eu)O12 A-site cuboctahedra and Ca(Eu)O6 B-site octahedra, partially accounting for the higher Λ values.
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