Photo-assisted conversion of tetracycline in regulated persulfate system: Multiple roles of natural dissolved organic matter

Advanced oxidation processes (AOPs) using persulfate system can effectively remove organic pollutants. However, dissolved organic matter (DOM) has multiple effects on AOPs efficiency, and the influence of DOMs from natural sources on AOPs is still unclear. In this study, we explored the effects of soil DOM (SDOM) and fertilizer DOM (FDOM) on tetracycline (TC) removal by persulfate systems. DOMs introduction decreased light transmittance, slightly increased the pH of the systems, and destroyed original adsorption-desorption equilibrium. SDOM promoted most reactive species generation in the initial stage, thus improving the initial TC degradation rate. However, introduction of SDOM and FDOM increased the final TC residual rate. FDOM produced more obvious inhibitory effects on TC degradation. The final TC residual rates in systems containing 7.5 and 15 mg L