生物炭
吸附
热解
化学
吸附
朗缪尔吸附模型
傅里叶变换红外光谱
朗缪尔
核化学
化学工程
有机化学
工程类
作者
Amita Shakya,Meththika Vithanage,Tripti Agarwal
标识
DOI:10.1016/j.envres.2022.114243
摘要
This study was envisaged to understand the effect of increasing pyrolysis temperature on the Cr(VI) removal potential of the groundnut shells derived biochars. The biochars were prepared at four different pyrolysis temperatures (350 °C, 450 °C, 550 °C, 650 °C) and were used unmodified to examine the adsorption potential for Cr(VI). Influence of biochar dose (1-10 g/L), pHinitial (2-10), Cr(VI)initial (10-500 mg/L) on Cr(VI) adsorptions; adsorption kinetics and isotherms were investigated. The observations suggested that the pyrolysis temperature is the key player in deciding the physicochemical properties as well the adsorption potential of the biochars. SEM and FTIR analysis suggested significant morphological and functional transformations in biochars with increasing pyrolysis temperature. The pHinitial was found to be the most profound adsorption parameter determining the adsorption potential of the biochars. The Cr(VI) adsorption capacity of the biochars decreased with the increase of the pyrolysis temperature (142.87-31.25 mg/L) as well as the solution pHinitial. All the biochars attained 100% removal efficiency with 50 mg/L of Cr(VI)initial and GNSB/350 achieved it in the minimum time (10 h) among all the biochars. GNSB/350 showed promising Langmuir adsorption capacity of 142.87 mg/L (pH 2, Tadsorption 30 °C, Cr(VI)initial 10-500 mg/L). In addition, the adsorption mechanism was found to be a synergistic action of chemi/physi-sorption with monolayer adsorption. Hence, the pyrolysis temperature significantly altered the physicochemical properties of the biochars, which highly influenced the adsorption performance of biochars.
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