过电位
杂原子
材料科学
化学工程
多孔性
电池(电)
纳米技术
析氧
兴奋剂
储能
碳纤维
碳化
电化学
化学
电极
复合材料
有机化学
扫描电子显微镜
光电子学
物理化学
工程类
功率(物理)
物理
复合数
量子力学
戒指(化学)
作者
Yumao Kang,Wei Wang,Jinmei Li,Sarah Imhanria,Yaxin Hao,Ziqiang Lei
标识
DOI:10.1016/j.jpowsour.2021.229665
摘要
Engineering highly efficient and robust porous carbon materials for the oxygen reduction and oxygen evolution reactions (ORR/OER) remains a great challenge for boosting the practical application of metal-air batteries. Herein, we report a carbonization-etching approach to achieve ultrathin B, N co-doped porous carbon nanosheets (BN–PCN) with hierarchically porous structure and large specific surface area (966.46 m2 g−1) using intumescent flame retardant (IFR) system. Owing to its unique structural features, the BN-PCN delivers high electrocatalytic ORR activity with a comparable half-wave potential of 0.84 V and superior stability to those of commercial Pt/C. Moreover, the BN-PCN exhibits a smaller overpotential for OER in comparison with singly doped counterparts, suggesting that the structural properties of BN-PCN play important roles in imparting the electrocatalytic activities of ORR and OER. Furthermore, BN-PCN-driven Zn-air battery demonstrates excellent power density (193.6 mW cm−2) and high energy efficiency. This study offers a promising avenue for designing multiple heteroatom-doped porous carbon materials for clean energy conversion and storage applications.
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