碱性水电解
电力转天然气
制氢
电解
可再生能源
环境科学
电解质
氢
氢气储存
工艺工程
可操作性
高压电解
材料科学
核工程
汽车工程
化学
计算机科学
电气工程
电极
工程类
物理化学
有机化学
软件工程
作者
Chang Zhang,Jinyi Wang,Zhibo Ren,Zhiyong Yu,Pengjie Wang
标识
DOI:10.1016/j.ijhydene.2021.08.029
摘要
Alkaline water electrolysis is the most promising approach for the industrial production of green hydrogen. This study investigates the dynamic operational characteristics of an industrial-scale alkaline electrolyzer with a rated hydrogen production of 50 m 3 /h. Strategies for system control and equipment improvement in dynamic-mode alkaline electrolytic hydrogen production are discussed. The electrolyzer can operate over a 30%–100% rated power load, thereby facilitating high-purity (>99.5%) H 2 production, competitive DC energy efficiency (4.01–4.51 kW h/Nm 3 H 2 , i.e., 73.1%–65.0% LHV), and good gas–liquid fluid balance. A safe H 2 content of 2% in O 2 (50% LFL) can be guaranteed by adjusting the system pressure. In transient operation, the electrolyzer can realize minute-level power and pressure modulation with high accuracy. The results confirm that the proposed alkaline electrolyzer can absorb highly fluctuating energy output from renewables because of its capability to operate in a dynamic mode. • Wind-powered 250 kW electrolyzer with rated hydrogen production of 50 m 3 /h. • Electrolyzer operability under partial power loads and transient states. • High-purity (>99.5%) H 2 production over a 30%–100% rated power load. • Minute-level power and pressure modulation with high accuracy. • Dynamic simulation experiments with fluctuating wind power input.
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