材料科学
光催化
兴奋剂
化学工程
氢
磷
纳米技术
光谱学
催化作用
光电子学
化学
有机化学
量子力学
物理
工程类
冶金
作者
Sijie Lv,Yun Hau Ng,Ruixue Zhu,Shuang Li,Chunxiao Wu,Yuxi Liu,Yafei Zhang,Lin Jing,Jiguang Deng,Hongxing Dai
标识
DOI:10.1016/j.apcatb.2021.120438
摘要
The design and synthesis of g-C3N4 with favourable physical-chemical architecture are important factors in influencing its photoactivity. Herein, a phosphorus (P) vapor assisted synthetic strategy was employed to fabricate the P-doped hollow g-C3N4 photocatalysts with ultrathin shell structure (< 25 nm in thickness). The doping of P and the compression of shell thickness of the hollow g-C3N4 were induced simultaneously by the P vapor during the heating process. The as-prepared P-doped ultrathin hollow g-C3N4 sphere (P/UH-CNS) photocatalysts exhibited enlarged surface area and light responsive range, and improved charge transportation efficiency by suppressing the charge recombination and self-trapping within g-C3N4. These resulted in a high photocatalytic hydrogen evolution rate of 9653 μmol h−1 g−1. The charge dynamics in this P/UH-CNS system was revealed in detail by using the ultrafast time-resolved spectroscopy.
科研通智能强力驱动
Strongly Powered by AbleSci AI