Multi-enzyme activity of three layers FeO @ZnMnFeO @Fe-Mn organogel for colorimetric detection of antioxidants and norfloxacin with smartphone

化学 检出限 柠檬酸 电子转移 氧化酶试验 过氧化氢酶 过氧化物酶 线性范围 没食子酸 核化学 无机化学 抗氧化剂 光化学 生物化学 色谱法
作者
Mengmeng Sun,Mingxia He,Jiang Shao-juan,Sheng Wang,Xianxiang Wang,Tao Liu,Chang Song,Suning Wang,Hanbing Rao,Zhiwei Lu
出处
期刊:Chemical Engineering Journal [Elsevier]
卷期号:425: 131823-131823 被引量:43
标识
DOI:10.1016/j.cej.2021.131823
摘要

In this study, the FeOx@ZnMnFeOy@Fe-Mn bimetallic organogel ([email protected]@FM-MOG) with three layers structure was synthesized. It presented outstanding multi-enzyme (peroxidase, oxidase and catalase) activities. The systematical characterization results showed that Zn and Mn on the surface of [email protected]@FM-MOG were nearly disappeared, and thus a large amount of Fe exposed as the active species. Accordingly, the high ratio of Fe2+/Fe3+ for [email protected]@FM-MOG was conductive to the electron transfer and enzyme activity. Moreover, the multiple detection platforms were constructed based on the different nanozyme activities. As for the peroxidase-mimetic activity, citric acid (CA) and norfloxacin (NOR) were monitored continuously on the basis of the turn on–off-on signal change due to the electron transfer abilities and hydroxyl radicals (•OH) formation. The linear range of 0.415–6.21 μM was obtained with a low detection limit of 79 nM, which was rarely detecting citric acid by nanozyme. And the low detection limit of 52 nM for NOR was superior to the most published NOR assays in nanozyme field. Furthermore, an oxidase platform for gallic acid (GA) was also established due to superoxide anions (O2•−) generation. It should be noted that the smartphone detection platforms for CA and NOR were established successfully for on-site analysis. This study provided multifunctional detection platform for valuating CA, NOR and GA in food quality and environment monitoring.
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