Carbon Nitride for the Selective Oxidation of Aromatic Alcohols in Water under Visible Light

ChemSusChemVolume 6, Issue 11 p. 2074-2078 Communication Carbon Nitride for the Selective Oxidation of Aromatic Alcohols in Water under Visible Light Baihua Long, Baihua Long Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this authorProf. Zhengxin Ding, Prof. Zhengxin Ding Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this authorProf. Xinchen Wang, Corresponding Author Prof. Xinchen Wang [email protected] Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this author Baihua Long, Baihua Long Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this authorProf. Zhengxin Ding, Prof. Zhengxin Ding Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this authorProf. Xinchen Wang, Corresponding Author Prof. Xinchen Wang [email protected] Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Research Institute of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, 350002 (PR China), Fax: (+86) 59183778608Search for more papers by this author First published: 26 August 2013 https://doi.org/10.1002/cssc.201300360Citations: 101Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract The selective oxidation of aromatic alcohols in water is achieved by using a carbon nitride (CN) catalyst, dioxygen, and visible light. The unique electronic structure of CN avoids the direct formation of hydroxyl radicals, which typically cause the total oxidation of organics. The chemical stability of CN allows several chemical protocols for photoredox catalysis in water, as exemplified by cooperative catalysis involving Brønsted acids. This leads to a new, green pathway for diverse organic transformations using sunlight and water. Supporting Information As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Filename Description cssc_201300360_sm_miscellaneous_information.pdf2.3 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1 1aG.-J. T. Brink, I. W. C. E. Arends, R. A. Sheldon, Science 2000, 287, 1636–1639; 1bR. A. Sheldon, I. W. C. E. Arends, G.-J. T. Brink, A. Dijksman, Acc. Chem. Res. 2002, 35, 774–781; 1cT. Mallat, A. Baiker, Chem. Rev. 2004, 104, 3037–3058; 1dB. N. Zope, D. D. Hibbitts, M. Neurock, R. J. Davis, Science 2010, 330, 74–78. 2 2aG. Cardillo, Chromium Oxidations in Organic Chemistry, Vol. 19, Springer, Berlin, 1984; 2bS. Velusamy, T. Punniyamurthy, Org. Lett. 2004, 6, 217–219; 2cS. Patel, B. K. Mishra, J. Org. 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