硅氢加成
催化作用
铱
试剂
三氟甲基
艾地明
化学
高分子化学
硼
有机化学
药物化学
烷基
作者
Yann Corre,Wissam Iali,Mustapha Hamdaoui,Xavier Trivelli,Jean‐Pierre Djukic,Francine Agbossou‐Niedercorn,Christophe Michon
摘要
Ir(iii) metallacycles were applied as catalysts for the hydrosilylation of ketimines and aldimines by using sodium tetrakis[(3,5-trifluoromethyl)phenyl]borate, NaBArF24, as an additive. By using a slight excess of the organosilane reagent, the reactions proceeded rapidly and efficiently, at low catalyst loadings and at room temperature.
科研通智能强力驱动
Strongly Powered by AbleSci AI