Synthesis of Prussian Blue Nanoparticles with a Hollow Interior by Controlled Chemical Etching

Angewandte Chemie International EditionVolume 51, Issue 4 p. 984-988 Communication Synthesis of Prussian Blue Nanoparticles with a Hollow Interior by Controlled Chemical Etching Dr. Ming Hu, Dr. Ming Hu World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this authorProf. Dr. Shuhei Furukawa, Prof. Dr. Shuhei Furukawa Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan)Search for more papers by this authorRyo Ohtani, Ryo Ohtani Graduate School of Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan)Search for more papers by this authorDr. Hiroaki Sukegawa, Dr. Hiroaki Sukegawa Spintronics Group, Magnetic Materials Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)Search for more papers by this authorDr. Yoshihiro Nemoto, Dr. Yoshihiro Nemoto World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this authorDr. Julien Reboul, Dr. Julien Reboul Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan)Search for more papers by this authorProf. Dr. Susumu Kitagawa, Prof. Dr. Susumu Kitagawa Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan) Graduate School of Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan)Search for more papers by this authorProf. Dr. Yusuke Yamauchi, Corresponding Author Prof. Dr. Yusuke Yamauchi yamauchi.yusuke@nims.go.jp World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan) Faculty of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555 (Japan) Precursory Research for Embryonic Science and Technology (PRESTO) (Japan) Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this author Dr. Ming Hu, Dr. Ming Hu World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this authorProf. Dr. Shuhei Furukawa, Prof. Dr. Shuhei Furukawa Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan)Search for more papers by this authorRyo Ohtani, Ryo Ohtani Graduate School of Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan)Search for more papers by this authorDr. Hiroaki Sukegawa, Dr. Hiroaki Sukegawa Spintronics Group, Magnetic Materials Unit, National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)Search for more papers by this authorDr. Yoshihiro Nemoto, Dr. Yoshihiro Nemoto World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this authorDr. Julien Reboul, Dr. Julien Reboul Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan)Search for more papers by this authorProf. Dr. Susumu Kitagawa, Prof. Dr. Susumu Kitagawa Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida, Sakyo, Kyoto 606-8501 (Japan) ERATO Kitagawa Integrated Pores Project (Japan) Science and Technology Agency (JST), Kyoto Research Park, Bldg #3, Shimogyo, Kyoto 600-8815 (Japan) Graduate School of Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan)Search for more papers by this authorProf. Dr. Yusuke Yamauchi, Corresponding Author Prof. Dr. Yusuke Yamauchi yamauchi.yusuke@nims.go.jp World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan) Faculty of Science and Engineering, Waseda University, 3-4-1 Ohkubo, Shinjuku, Tokyo 169-8555 (Japan) Precursory Research for Embryonic Science and Technology (PRESTO) (Japan) Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)World Premier International (WPI) Research Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)Search for more papers by this author First published: 16 December 2011 https://doi.org/10.1002/anie.201105190Citations: 340Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare 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Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract A facile route has been found to prepare Prussian blue (PB) hollow particles with a cubic shape (see picture). With PB mesocrystals used as a starting material, hollow interiors were created through controlled chemical etching in the presence of poly(vinylpyrrolidone). The hollow cavities and particle sizes could be tuned by changing the synthetic conditions, and the original PB crystallinity was preserved even after formation of interior hollows. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201105190_sm_miscellaneous_information.pdf3.9 MB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume51, Issue4January 23, 2012Pages 984-988 RelatedInformation