铀
催化作用
惰性
过渡金属
化学
金属
纳米技术
放射化学
组合化学
无机化学
材料科学
有机化学
冶金
作者
A.R. Fox,Suzanne C. Bart,Karsten Meyer,Christopher C. Cummins
出处
期刊:Nature
[Springer Nature]
日期:2008-09-01
卷期号:455 (7211): 341-349
被引量:409
摘要
The forefront of research into the complexes of uranium reveals chemical transformations that challenge and expand our view of this unique element. Certain ligands form multiple bonds to uranium, and small, inert molecules such as nitrogen and carbon dioxide become reactive when in complex with the metal. Such complexes provide clues to the catalytic future of uranium, in which the applications of the element extend far beyond the nuclear industry. Most excitingly, the ability of uranium to use its outermost f electrons for binding ligands might enable the element to catalyse reactions that are impossible with conventional, transition-metal catalysts.
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