化学
对映选择合成
催化作用
克莱森重排
立体化学
有机化学
组合化学
作者
Elizabeth C. Linton,Marisa C. Kozlowski
摘要
The first catalytic, enantioselective Meerwein−Eschenmoser Claisen rearrangement has been achieved. Palladium(II) BINAP or phosphinooxazoline catalysts were employed to generate oxindole products with 100% conversion and up to 92% ee.
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