材料科学
阴极
拉曼光谱
X射线光电子能谱
扫描电子显微镜
扫描透射电子显微镜
化学工程
透射电子显微镜
锂(药物)
纳米技术
复合材料
化学
物理化学
内分泌学
工程类
物理
光学
医学
作者
Yawei Chen,Jianming Li,Zhanwu Lei,Yakun Huo,Lanlan Yang,Suyuan Zeng,Honghe Ding,Yi Qin,Yulin Jie,Fanyang Huang,Qi Li,Junfa Zhu,Ruiguo Cao,Genqiang Zhang,Shuhong Jiao,Dongsheng Xu
标识
DOI:10.1002/aenm.201903401
摘要
Abstract Transition metal sulfides hold promising potentials as Li‐free conversion‐type cathode materials for high energy density lithium metal batteries. However, the practical deployment of these materials is hampered by their poor rate capability and short cycling life. In this work, the authors take the advantage of hollow structure of CuS nanoboxes to accommodate the volume expansion and facilitate the ion diffusion during discharge–charge processes. As a result, the hollow CuS nanoboxes achieve excellent rate performance (≈371 mAh g −1 at 20 C) and ultra‐long cycle life (>1000 cycles). The structure and valence evolution of the CuS nanobox cathode are identified by scanning electron microscopy, transmission electron microscopy, and X‐ray photoelectron spectroscopy. Furthermore, the lithium storage mechanism is revealed by galvanostatic intermittent titration technique and operando Raman spectroscopy for the initial charge–discharge process and the following reversible processes. These results suggest that the hollow CuS nanobox material is a promising candidate as a low‐cost Li‐free cathode material for high‐rate and long‐life lithium metal batteries.
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