Mass-transfer processes in the adsorption of crystal violet by activated carbon derived from pomegranate peels: Kinetics and thermodynamic studies

结晶紫 吸附 活性炭 零电荷点 弗伦德利希方程 化学 朗缪尔 水溶液 动力学 核化学 色谱法 有机化学 医学 物理 病理 量子力学
作者
Moussa Abbas,Zahia Harrache,M. Trari
出处
期刊:Journal of Engineered Fibers and Fabrics [SAGE Publishing]
卷期号:15: 155892502091984-155892502091984 被引量:34
标识
DOI:10.1177/1558925020919847
摘要

This study investigates the potential use of activated carbon, prepared from pomegranate peels, as an adsorbent activated using H 3 PO 4 and its ability to remove crystal violet from an aqueous solution. The adsorbent was characterized by the Brunauer–Emmett–Teller method (specific surface area: 51.0674 m 2 g −1 ) and point of zero charge (pH PZC = 5.2). However, some examined factors were found to have significant impacts on the adsorption capacity of activated carbon derived from pomegranate peels such as the initial dye concentration (5–15 mg L −1 ), solution pH (2–14), adsorbent dose (1–8 g L −1 ), agitation speed (100–700 r/min), and temperature (298–338 K). The best adsorption capacity was found at pH 11 with an adsorbent dose of 1 g L −1 , an agitation speed at 400 r/min, and a contact time of 45 min. The adsorption mechanism of crystal violet onto activated carbon derived from pomegranate peels was studied using the pseudo-first-order, pseudo-second-order, Elovich, and Webber–Morris diffusion models. The adsorption kinetics were found to rather follow a pseudo-second order kinetic model with a determination coefficient ( R 2 ) of 0.999. The equilibrium adsorption data for crystal violet adsorbed onto activated carbon derived from pomegranate peels were analyzed by the Langmuir, Freundlich, Elovich, and Temkin models. The results indicate that the Langmuir model provides the best correlation with q max capacities of 23.26 and 76.92 mg g −1 at 27°C and 32°C, respectively. The adsorption isotherms at different temperatures have been used for the determination of thermodynamic parameters like the free energy, enthalpy, and entropy to predict the nature of adsorption process. The negative values Δ G 0 (−5.221 to −1.571 kJ mol −1 ) and Δ H 0 (−86.141 kJ mol −1 ) indicate that the overall adsorption is spontaneous and exothermic with a physisorption process. The adsorbent derived from pomegranate peels was found to be very effective and suitable for the removal of reactive dyes from aqueous solutions, due to its availability, low-cost preparation, and good adsorption capacity.
最长约 10秒,即可获得该文献文件

科研通智能强力驱动
Strongly Powered by AbleSci AI
更新
PDF的下载单位、IP信息已删除 (2025-6-4)

科研通是完全免费的文献互助平台,具备全网最快的应助速度,最高的求助完成率。 对每一个文献求助,科研通都将尽心尽力,给求助人一个满意的交代。
实时播报
郑桂庆完成签到 ,获得积分10
刚刚
zhang完成签到 ,获得积分10
刚刚
yuchen完成签到,获得积分10
1秒前
喜悦的水云完成签到 ,获得积分10
1秒前
2秒前
zhaokunfeng完成签到,获得积分10
2秒前
Y123发布了新的文献求助10
2秒前
wu完成签到,获得积分10
2秒前
高高诗柳完成签到 ,获得积分10
2秒前
王金豪完成签到,获得积分10
2秒前
LSS完成签到,获得积分10
2秒前
榜一大哥的负担完成签到 ,获得积分10
3秒前
Lucas应助qi0625采纳,获得10
3秒前
顾矜应助以筱采纳,获得10
4秒前
景清完成签到,获得积分10
4秒前
细心香烟完成签到 ,获得积分10
4秒前
hu完成签到 ,获得积分10
4秒前
HQ完成签到,获得积分10
4秒前
5秒前
水清木华完成签到,获得积分10
5秒前
6秒前
miao完成签到,获得积分20
6秒前
xyp_zjut应助学术乞丐采纳,获得10
6秒前
Lucas应助凉白开采纳,获得10
6秒前
体贴凌柏发布了新的文献求助10
7秒前
7秒前
7秒前
鹿子完成签到 ,获得积分10
7秒前
秋枫忆完成签到,获得积分10
9秒前
宋立发布了新的文献求助10
9秒前
孤独的AD钙完成签到,获得积分10
9秒前
10秒前
fang应助miao采纳,获得10
11秒前
星辰与月完成签到,获得积分10
11秒前
Pt-SACs发布了新的文献求助10
11秒前
安静无招完成签到 ,获得积分10
15秒前
lqphysics完成签到,获得积分10
16秒前
Jerry完成签到 ,获得积分10
16秒前
枕星发布了新的文献求助10
16秒前
全职法师刘海柱完成签到,获得积分10
18秒前
高分求助中
【提示信息,请勿应助】关于scihub 10000
Les Mantodea de Guyane: Insecta, Polyneoptera [The Mantids of French Guiana] 3000
徐淮辽南地区新元古代叠层石及生物地层 3000
The Mother of All Tableaux: Order, Equivalence, and Geometry in the Large-scale Structure of Optimality Theory 3000
Handbook of Industrial Diamonds.Vol2 1100
Global Eyelash Assessment scale (GEA) 1000
Picture Books with Same-sex Parented Families: Unintentional Censorship 550
热门求助领域 (近24小时)
化学 材料科学 医学 生物 工程类 有机化学 生物化学 物理 内科学 纳米技术 计算机科学 化学工程 复合材料 遗传学 基因 物理化学 催化作用 冶金 细胞生物学 免疫学
热门帖子
关注 科研通微信公众号,转发送积分 4038368
求助须知:如何正确求助?哪些是违规求助? 3576068
关于积分的说明 11374313
捐赠科研通 3305780
什么是DOI,文献DOI怎么找? 1819322
邀请新用户注册赠送积分活动 892672
科研通“疑难数据库(出版商)”最低求助积分说明 815029