电催化剂
材料科学
塔菲尔方程
介孔材料
氮化物
析氧
三元运算
催化作用
钴
电解质
过渡金属
纳米技术
分解水
化学工程
无机化学
过电位
冶金
电化学
电极
有机化学
化学
程序设计语言
图层(电子)
物理化学
工程类
光催化
计算机科学
作者
Ali Saad,Zhixing Cheng,Jing Wang,Siqi Liu,Minghui Yang,Tiju Thomas,Jiacheng Wang,Minghui Yang
标识
DOI:10.1002/admi.201900960
摘要
Abstract Transition metal nitrides are of considerable interest for energy conversion and storage applications. Given this, synthesis of nanostructured 3D transition metal nitrides is of contemporary interest. Here, a hard templating simple and efficient pathway to synthesize 3D ordered‐mesoporous ternary nitrides NiCo 2 N is reported using the mesoporous silica KIT‐6 hard template. Benefitting from its large surface area and accessible pores, uniform shape, and enhanced infiltration capacity for electrolyte, mesoporous NiCo 2 N demonstrates superior electrode performance for oxygen evolution reaction (OER) in alkaline medium. As‐synthesized mesoporous ternary nitride NiCo 2 N shows desirable performance with very low overpotential (289 mV), and yields ≈10 mA cm −2 geometric current density. This is lower than the values of IrO 2 and that of mesoporous binary nitrides CoN and Ni 3 N electrocatalysts. NiCo 2 N shows a small Tafel slope and smallest semicircle. Moreover, as‐synthesized NiCo 2 N exhibits low loss of activity after 10 h test for OER in alkaline solution. This work explores a promising way to produce OER electrocatalyst Co–Ni‐based ternary nitrides for water splitting applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI