拉曼光谱
插层(化学)
碳纤维
相间
电解质
材料科学
钠
化学
化学工程
分析化学(期刊)
无机化学
电极
物理化学
环境化学
冶金
复合数
光学
物理
工程类
生物
遗传学
复合材料
作者
Julia S. Weaving,A.Y.K. Lim,Jason Millichamp,Tobias P. Neville,Daniela Ledwoch,Emma Kendrick,Paul F. McMillan,Paul R. Shearing,Christopher A. Howard,Dan J. L. Brett
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2020-08-11
卷期号:3 (8): 7474-7484
被引量:64
标识
DOI:10.1021/acsaem.0c00867
摘要
Operando microbeam Raman spectroscopy is used to map the changes in hard carbon during sodiation and desodiation in unprecedented detail, elucidating several important and unresolved aspects of the sodiation mechanism. On sodiation a substantial, reversible decrease in G-peak energy is observed, which corresponds directly to the sloping part of the voltage profile and we argue can only be due to steady intercalation of sodium between the turbostratic layers of the hard carbon. The corresponding reversibility of the D-peak energy change is consistent with intercalation rather than representing a permanent increase in disorder. No change in energy of the graphitic phonons occurs over the low-voltage plateau, indicating that intercalation saturates before sodium clusters form in micropores in this region. At the start of the initial sodiation there is no change in G- and D-peak energy as the solid electrolyte interphase (SEI) forms. After SEI formation, the background slope of the spectra increases irreversibly due to fluorescence. The importance of in situ/operando experiments over ex situ studies is demonstrated; washing the samples or air exposure causes the G- and D-peaks to revert back to their original states because of SEI removal and sodium deintercalation and confirms no permanent damage to the carbon structure.
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