溴化乙锭
阳光
降级(电信)
纳米复合材料
光催化
致癌物
溴化物
光降解
光化学
化学
材料科学
化学工程
核化学
纳米技术
无机化学
光学
计算机科学
有机化学
生物化学
物理
DNA
催化作用
工程类
电信
作者
Ahmed M. Youssef,Dalal A. Abou El Ella,Hala Ghannam,Abdallah F. Zedan,Wael M. Aboulthana,Al-Sayed Al-Sherbini
出处
期刊:Egyptian Journal of Chemistry
日期:2020-02-10
卷期号:63 (5): 5-9
被引量:7
标识
DOI:10.21608/ejchem.2020.21987.2313
摘要
Ethidium bromide (EtBr) is one of the most broadly used dyes in molecular biology laboratories. It was considered a strong mutagenic, carcinogenic and possesses a major safety problem for the researchers and environmental hazards during the disposal process. In the current study chitosan (CS) and polyvinylidene chloride (PVDC) based on different morphologies of TiO2-Au nanocomposites were prepared, namely as CS/PVDC/TiO2-Au nanocomposites. Firstly, the titanium dioxide nanowires (TiO2-NWs, gold nanoparticles (Au-NPs) and TiO2-NWs doped by Au-NPs (TiO2-Au) were successfully fabricated and well-evaluated using X-ray diffractometer (XRD) and transmission electron microscope (TEM). Furthermore, chitosan was prepared from crabs shell wastes and blended with PVDC then different loadings of TiO2-Au nanocomposites were incorporated onto the nanocomposites films. The prepared CS/PVDC/TiO2-Au nanocomposites films were characterized using UV-Visible spectra, Fourier transforms infrared (FT-IR), XRD and TEM. Moreover, the CS/PVDC/TiO2-Au nanocomposites were used for photodecomposition of EtBr under sunlight irradiation from~ 400-600 W/m2 with and without aeration as well as assaying integrity of the EtBr after decomposition by horizontal gel electrophoresis. The results established that the CS/PVDC/TiO2-Au nanocomposites were sufficient to remove ~70-90 % of the EtBr through the irradiated time course and ~ 60 % of the dye was degraded in the first one hour.
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