纳米片
硫黄
材料科学
热解
碳纤维
电化学
电池(电)
硫化物
硫化铁
化学工程
锂(药物)
阳极
纳米花
吸附
纳米技术
化学
电极
复合数
冶金
复合材料
有机化学
纳米结构
功率(物理)
物理化学
医学
量子力学
内分泌学
工程类
物理
作者
Rongrong Li,Hangjia Shen,Erum Pervaiz,Minghui Yang
标识
DOI:10.1016/j.cej.2020.126462
摘要
As the vital component affecting the performance of lithium-sulfur (Li-S) battery, the cathode host materials are of great importance. In order to pursue the high sulfiphility to obtain good performance, vast environmentally hazardous heavy metals were introduced, increasing the production costs and hindering Li-S battery real application to a certain extent. Along with performance, cost and environmental safety are keys but neglected point, for scalable fabrication of Li-S batteries host material. Here, an economical, efficient yet green adsorbent N-doped carbon-coated iron sulfide (abbreviated as FeS/N-C) has been synthesized via a simple pyrolysis approach. The achieved FeS/N-C exhibits rich element doping of nitrogen and uniform nanosheet morphology, self-assembling into stable nanoflower structures. As a sulfur host, the FeS/N-C not only avoids the introduction of the precarious heavy metals, reduces costs but also presents high sulfiphility to achieve extraordinary electrochemical performance. With a sulfur content of 70.8 wt%, the FeS/N-C based sulfur electrodes deliver a high reversible capacity of about 729 mA h/g at 0.5 C after 500 cycles, with the degradation of 0.013% per cycle. Even at a higher rate of 2.0 C, a reversible capacity of 438 mA h/g still remains after 1000cycles. This green and highly efficient host material provides cost-effective solution to large-scale commercial applications of Li-S battery.
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