3D Hollow α‐MnO2 Framework as an Efficient Electrocatalyst for Lithium–Oxygen Batteries

Abstract Lithium–oxygen (Li–O 2 ) batteries are attracting more attention owing to their superior theoretical energy density compared to conventional Li‐ion battery systems. With regards to the catalytically electrochemical reaction on a cathode, the electrocatalyst plays a key role in determining the performance of Li–O 2 batteries. Herein, a new 3D hollow α‐MnO 2 framework (3D α‐MnO 2 ) with porous wall assembled by hierarchical α‐MnO 2 nanowires is prepared by a template‐induced hydrothermal reaction and subsequent annealing treatment. Such a distinctive structure provides some essential properties for Li–O 2 batteries including the intrinsic high catalytic activity of α‐MnO 2 , more catalytic active sites of hierarchical α‐MnO 2 nanowires on 3D framework, continuous hollow network and rich porosity for the storage of discharge product aggregations, and oxygen diffusion. As a consequence, 3D α‐MnO 2 achieves a high specific capacity of 8583 mA h g −1 at a current density of 100 mA g −1 , a superior rate capacity of 6311 mA h g −1 at 300 mA g −1 , and a very good cycling stability of 170 cycles at a current density of 200 mA g −1 with a fixed capacity of 1000 mA h g −1 . Importantly, the presented design strategy of 3D hollow framework in this work could be extended to other catalytic cathode design for Li–O 2 batteries.