纳米片
材料科学
化学工程
纳米颗粒
碳纤维
兴奋剂
离子
多孔性
纳米技术
有机化学
复合材料
复合数
光电子学
工程类
化学
作者
Baosong Li,Baojuan Xi,Fangfang Wu,Hongzhi Mao,Jing Liu,Jinkui Feng,Shenglin Xiong
标识
DOI:10.1002/aenm.201803070
摘要
Abstract In spite of the satisfactory advancement in preparing TiO 2 ‐based hybrid structures, most methods rely on additional template‐based multistep reactions for engineering the given structure. Herein, a unique self‐template and in situ recrystallization strategy is explored to synthesize uniform flowerlike multicompositional structures of nitrogen‐doped porous carbon nanosheet networks immobilizing TiO 2 nanoparticles (TiO 2 ∩NPCSs) via a self‐prepared single precursor and subsequent thermal treatment. Depending on the unique coordination ability of 2,4‐dihydroxybenzoic acid with metal ions under alkaline conditions to form a flowerlike network, a self‐produced single precursor can be achieved. Careful investigations of the self‐prepared precursor reveal a high practicability of the present synthetic scheme. Because of the novel structural and compositional features, these TiO 2 ∩NCSN flowers indicate superior sodium storage properties when evaluated as anodes for sodium‐ion batteries. Impressively, the TiO 2 ∩NCSN flowers deliver high reversible capacities of 152 mAh g −1 at 2C for 3000 cycles and 114 mAh g −1 at 10C for 10000 cycles, as well as an ultrahigh rate capability up to 50C with a capacity of 101 mAh g −1 . The facile method could stimulate further capability in precise construction of complex architectures with complicated compositions for different device applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI