材料科学
准直器
光纤
光学
甲烷
体积热力学
激光器
检出限
光谱学
乙炔
吸收(声学)
原位
吸收光谱法
泄漏(经济)
分析化学(期刊)
化学
物理
复合材料
有机化学
色谱法
量子力学
经济
宏观经济学
作者
Di Yu,Ling Yu,Y. Zee,Yuechong Shi,Fang Song,Yiding Wang,Frank K. Tittel,Chuantao Zheng
标识
DOI:10.1016/j.infrared.2022.104141
摘要
Long-distance field gas sensing in hazardous environment is highly desirable in industry but remains challenging due to ultralow concentration levels of the target gas species. A fiber-coupled Herriott cell (FC-HC) was fabricated for long-distance gas detection, which is composed of a sealed Herriott cell with a dimensional size of 8.3 cm × 9.0 cm × 47.2 cm, a single-mode fiber collimator for input light coupling and a multi-mode optical fiber for output light coupling. The experimentally measured absorption path length of the FC-HC is ∼24.6 m through acetylene (C2H2) detection. Also, this FC-HC is compatible with distributed feedback lasers operating from ∼1.5 μm to ∼2.3 μm. C2H2 and methane (CH4) measurements were carried out using the fabricated FC-HC. The measurement precision of C2H2 is 0.38 parts-per-million in volume (ppmv) with a 0.5 s averaging time, which can be further decreased to 27.20 parts-per-billion in volume (ppbv) with a 70 s averaging time. The limit of detection (LoD) of CH4 is 1.11 ppmv with an averaging time of 0.5 s and can be improved to 0.04 ppmv with an averaging time of 122 s. Field measurement of the sensor system for in-situ CH4 leakage was performed to validate the normal operation of the system. The proposed FC-HC shows potential applications in the field of long-distance gas sensing based on laser absorption spectroscopy.
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