双金属片
介孔材料
碳化
化学工程
金属有机骨架
热解
化学
纳米颗粒
材料科学
纳米技术
无机化学
催化作用
吸附
有机化学
工程类
作者
Syed Shoaib Ahmad Shah,Lishan Peng,Tayyaba Najam,Chao Cheng,Guangping Wu,Yan Nie,Wei Ding,Xueqiang Qi,Siguo Chen
标识
DOI:10.1016/j.electacta.2017.08.091
摘要
Metal organic frameworks (MOFs) have been considered as promising candidates for excellent electrocatalysts. Herein, we report a controllable synthesis of Co-N-C electrocatalysts derived from Zn/Co bimetallic organic frameworks (Zn/Co-MOFs). The elimination of Zn is simultaneously taken place during the pyrolysis due to its low boiling point, resulting in a very mesoporous assembly with homogeneous Co distribution in N-C framework. Zn also facilitates the dispersion of Co in the Zn/Co-MOF, which efficiently hinders the agglomeration of Co during carbonization. The results show that Co-N-C catalysts synthesized from 22.5% Co containing in the Zn/Co-MOF precursor gives the best ORR activity in alkaline solution with its half wave potential of 0.91 V vs. RHE and current density of 3.0 mA/cm2, which is even better than those of commercial Pt/C catalysts. The high activity and current density are mainly attributed to the extremely well dispersed Co nanoparticles and the mesoporous nature.
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