材料科学
压力(语言学)
活化能
过饱和度
金属
铜
复合材料
冶金
热力学
化学
物理
哲学
语言学
有机化学
作者
Ennis T. Ogawa,J. W. McPherson,J. Rosal,K.J. Dickerson,Tz-Cheng Chiu,Lancy Tsung,Manoj Kumar Jain,T. Bonifield,J.C. Ondrusek,W.R. McKee
标识
DOI:10.1109/relphy.2002.996654
摘要
Stress-induced voiding is observed in Cu-based, deep-submicron, dual-damascene technologies where voids are formed under the via when the via connects to a wide metal lead below it. The voiding results from the supersaturation of vacancies that develops due to grain growth when the Cu is not properly annealed prior to being fully constrained. The driving force for voiding is shown to be stress migration with a maximum in voiding rate observed at /spl sim/190/spl deg/C. A diffusional model is presented which shows that the voiding mechanism is an issue primarily for vias connected to wide Cu leads. A thermomechanical stress exponent of 3.2 and a diffusional activation energy of 0.74 eV were determined for this stress-induced voiding mechanism.
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