Nanoconfinement and Catalytic Dehydrogenation of Ammonia Borane by Magnesium‐Metal–Organic‐Framework‐74

Trapped and released: Ammonia borane (AB) incorporated within the one-dimensional hexagonal nanopores of magnesium-metal–organic-framework-74 shows clean and exceptionally improved H2-release properties when compared to pristine AB (see figure; C gray, O red, Mg green, H white, N blue, B orange). In this system, the kinetics and the temperature of AB dehydrogenation can be easily tuned. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.