Actuation performance of a liquid crystalline elastomer composite reinforced by eiderdown fibers

Liquid crystalline elastomer (LCE) materials have been developed and investigated for several decades. One important obstacle, which impedes the practical industrial application of LCE materials, is their modest robustness as actuator materials. In this work, we developed a LCE composite which was fabricated by incorporating eiderdown fibers into a polysiloxane-based main-chain LCE matrix. The eiderdown fibers were used as the flexible reinforcement phase suitable for the shape-morphing performance of LCE materials upon being stimulated. Due to the long fiber property, specific structure and surface characteristics of the eiderdown fibers, they constructed a reinforcement network in the LCE matrix and formed tight interfacial adhesion with the matrix. The LCE composite demonstrated enhanced actuation mechanical properties and robust actuation performance. Its actuation blocking stress and modulus were increased due to the reinforcement effect of the eiderdown fibers. The tensile strength and the performance of anti-fatigue failure under repeated actuation cycles and high loadings were greatly improved due to the crack-resisting effect and bridging effect of the eiderdown fibers. While other properties, such as the liquid crystalline phase structure, the stimulus deformation ratio, phase transition temperature of the LCE matrix, etc., did not deteriorate or change due to the high flexibility, thermal stability and chemical stability of the eiderdown fibers.