极化(电化学)
欧姆接触
电解质
介电谱
材料科学
磁滞
分析化学(期刊)
电压
电阻抗
时间常数
停留时间
化学
电化学
复合材料
电极
电气工程
凝聚态物理
色谱法
物理
物理化学
工程类
医学
临床心理学
图层(电子)
作者
Alfredo Iranzo,Sergio J. Navas,Javier Pino,N. A. Althubiti,Mohamed R. Berber
标识
DOI:10.1016/j.electacta.2022.140809
摘要
The extent of the cell voltage hysteresis observed in polarization curves of PEM fuel cells and the origins causing this effect are investigated by performing experimental polarization curves with different dwell times for a 50 cm2 PEM fuel cell. Electrochemical Impedance Spectroscopy measurements are carried out in order to determine the relative contributions of the different polarizations (ohmic, activation, and concentration polarization). Equivalent circuits were obtained from the impedance spectra, where the interpretation of the circuit parameters enabled the analysis of the origin and extent of the cell voltage hysteresis. It was identified that the cause of the cell voltage hysteresis is actually dominated by the changes in the concentration polarization at low current densities, and by the changes in the activation polarization at high current densities. The cell ohmic resistance (and consequently the membrane hydration) presents a minor effect on the cell voltage hysteresis. The effect of the dwell time in the cell voltage hysteresis (with values ranging from 15 to 25 mV) presents a mixed trend, with an initial decrease for increasing dwell times from 120 to 600 s, and a later increase and a final almost constant hysteresis for longer dwell times.
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