A facile and binder-free coating method, termed Langmuir–Blodgett–Scooping, is reported. The method takes advantage of Marangoni stresses and self-assembly to rapidly create functional coating films of various nanomaterials, with single-particle thickness resolution, at an air–water interface (left). Transfer of the film to a conventional separator yields membranes that enhance cathode material utilization in lithium–sulfur batteries (right). As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.