噻唑
光化学
极性(国际关系)
分子内力
质子
激发态
有机发光二极管
化学
白光
二极管
材料科学
光电子学
立体化学
有机化学
物理
图层(电子)
量子力学
核物理学
生物化学
细胞
作者
Zhiyun Zhang,Yi‐An Chen,Wen‐Yi Hung,Wei‐Feng Tang,Yen‐Hao Hsu,Chi‐Lin Chen,Fan‐Yi Meng,Pi‐Tai Chou
标识
DOI:10.1021/acs.chemmater.6b04707
摘要
By using the thiazolo[5,4-d]thiazole (TzTz) moiety as the core of a proton acceptor, compounds 2,2′-(thiazolo[5,4-d]thiazole-2,5-diyl)bis(4-tert-butylphenol) (t-HTTH) and 4-tert-butyl-2-(5-(5-tert-butyl-2-methoxyphenyl)thiazolo[5,4-d]thiazol-2-yl)phenol (t-MTTH) have been strategically designed and synthesized. Upon photoexcitation, both t-HTTH and t-MTTH undergo a reversible type excited-state intramolecular proton transfer (ESIPT), the underlying mechanism of which has been verified by femtosecond early relaxation dynamics in various solvents. The pre-equilibrium in the excited state leads to both normal (∼440 nm) and proton-transfer tautomer (∼560 nm) emissions, for which the intensity ratio is dependent on both the molecular structure and the polarity of surrounding media. As a result, the emission can be widely tuned from blue to yellow via white-light luminescence. On the basis of t-MTTH, a white organic light emitting diode (WOLED) was successfully fabricated, which achieved external quantum efficiency (ηext) of 1.70% with Commission Internationale de L'Eclairage coordinates of (0.29, 0.33). More importantly, the electroluminescent spectra show superior color stability that is independent of luminance. The result demonstrates for the first time a credible WOLED based on a unimolecular ESIPT reaction, which may have far-reaching implications for practical application.
科研通智能强力驱动
Strongly Powered by AbleSci AI