化学
呋喃
二硒醚
组合化学
产量(工程)
串联
相容性(地球化学)
有机化学
电化学
功能群
化学工程
硒
工程类
物理化学
复合材料
冶金
材料科学
聚合物
电极
作者
Debabrata Maiti,Atreyee Halder,Aswathy Sasidharan Pillai,Suman De Sarkar
标识
DOI:10.1021/acs.joc.1c01688
摘要
The current method represents an electrochemically driven synthetic route to access polysubstituted selenofuran derivatives through the diselenide-promoted cyclization of homopropargyl alcohols. The tandem electro-oxidative transformation operates at ambient temperature and in the absence of an external oxidant. This mild and efficient methodology exhibits good functional group compatibility, providing a broad range of substrate scopes up to 84% isolated yield. Further conversion of the seleno-functionality afforded other valuable furan derivatives.
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