Development of a cleaner route for Aluminum–Vanadium alloy production

Aluminum–Vanadium (AlV) alloy is essential for high-performance titanium material. Calcium fluoride (CaF2) is currently used in AlV production and has inevitable drawbacks in terms of product quality and environmental impact. In order to avoid its potential hazards, lime (CaO) as an alternative flux material in producing AlV alloy has been investigated in laboratory and by industrial trials in the present study. The samples were analyzed by Electron Probe X-ray Micro-analyzer (EPMA) and X-ray Diffraction (XRD), regarding the phases formed and corresponding compositions. A slag with good fluidity can protect inner alloy from being oxidized and also promotes the separation between slag and alloy, with a goal to reduce alloy inclusions in slag to enhance the yield. The results showed that using CaO as flux with appropriate amount greatly improved the yield and quality of the AlV alloy and avoided environmental pollution caused by fluoride evaporations.