1D chains, 2D networks and 3D interdigitated frameworks of isoorotic acid or 4,4′-bipyridyl and isoorotic acid: syntheses, structures, and sorption properties

Five new coordination polymers, from 1D chains to a 2D sheet and finally 3D porous frameworks, have been synthesized with different transition metals. The 3D interdigitated framework of Ni(ii) is explored further for stepwise CO₂ and C₂H₂ storage.