钝化
材料科学
掺杂剂
钙钛矿(结构)
兴奋剂
化学工程
能量转换效率
纳米技术
光伏系统
光电子学
佩多:嘘
共轭体系
聚合物
聚电解质
薄膜
太阳能电池
光电流
热稳定性
光活性层
带隙
复合材料
电气工程
图层(电子)
工程类
作者
Helin Wang,Jiatao Wu,Jun Song,Junle Qu,Jiarong Lian,Peng‐Cheng Qian,Wai Yeung Wong
标识
DOI:10.1016/j.cej.2020.128068
摘要
Perovskite solar cells (PSCs) have achieved great success in the past few years because of outstanding photovoltaic performance. However, the existence of electronic trap states in the perovskite film is an obstacle for the fabrication of high-performance and stable PSCs. Herein, a linear conjugated polyelectrolyte was developed and employed as a dopant to improve the performance and stability of the perovskite film. The PPNNA doping can passivate surface defects to reduce the electronic trap states in the perovskite film, while simultaneously enhancing the electron extraction and transport to achieve high-efficiency solar cells. Furthermore, the PPNNA-doped perovskite film shows better stability from efficient surface passivation. The optimal 0.4% PPNNA-doped device exhibits better photovoltaic efficiency (20.38%) with enhanced device stability as compared to the control device (18.51%). This novel method by doping with the conjugated polyelectrolyte provides a pathway to fabricate high-efficiency and stable inverted PSCs.
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