Effect of oil extraction on physicochemical and structural properties of starch isolated from acorn (Quercus brantii).

Acorn (Quercus brantii) is a rich source of starch. Since the presence of lipids affects the physicochemical properties of starch and the extraction of nutritious acorn oil and its starch is economical, it's essential to study the acorn starch characteristics before and after oil extraction. Firstly, the best condition for reaching the maximum extraction yield of acorn starch (AS) was determined, and defatted acorn starch (DAS) was extracted in the same conditions. Then the physicochemical properties of both samples were compared. The structural properties were investigated by Scanning Electron Microscopy images. The maximum yield of AS was obtained in a 1:10 ratio (acorn flour: water) at 45 °C and 180 min. Results demonstrated significant differences between color parameters and fat content (0.65 ± 0.04 and 12 ± 0.02) of AS and DAS. Also, DAS had higher swelling power, solubility, and lower turbidity than AS. The X-ray diffraction pattern showed that AS was C-type with relative crystallinity of 27.77 %. Pasting, thermal, and textural properties reflected the higher viscosity, gelatinization, retrogradation, and hardness for DAS compared to AS. Consequently, all of these analyses exhibited structural changes in acorn starch by removing lipids from acorn flour and provided essential information for further applications of acorn starch in different industries.