材料科学
电解质
阳极
锂(药物)
氧化物
陶瓷
化学工程
图层(电子)
金属
硫化物
阴极
复合材料
冶金
电极
化学
物理化学
医学
内分泌学
工程类
作者
Kexin Xiao,Pengfei Ren,Xiaofen Wang,Hong Chen,Qiong Zhou
标识
DOI:10.1016/j.matlet.2024.136221
摘要
The interfacial stability, particularly between lithium metal and the solid electrolyte, as a critical challenge in solid-state batteries leads to rapid lithium-dendrite growth and increased internal resistance. In this study, we tackled these issues by developing a stable interface between sulfide electrolytes Li5.5PS4.5Cl1.5 (LPSCl) and the metallic lithium anode, using a polyethylene oxide (PEO) layer integrated with Li-ion conducting oxide electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP). The uniform distribution of LATP within the PEO matrix through a simple stirring process enhanced the mechanical strength of the PEO interlayer and minimizes both the interfacial reactions and lithium dendrite formation. A Li/Li symmetric cell incorporating this LATP-integrated layer exhibited a low interfacial resistance, ensuring stable cycling for 2800 h at a current density of 0.2 mA cm−2 at 60 °C.
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