Investigation of the use of glycerin as a by-product, pomace oil and paper wastewater as grinding aids in marble dust wastes

Waste management in marble processing plants is a considerable problem in countries with developed stone industries and trade. Research on the utilization of stone waste in different fields is still continuing. However, there are few studies on using this stone waste from processing plants as mineral fillers. Moreover, no study in the literature has investigated the influence of grinding aids on stone properties. The current research is the first to compare of the efficiency of different grinding aids on the waste calcitic and dolomitic marble in the production of mineral fillers. The objective of this work is to research the impacts of waste and by-products on the dry grinding of stone wastes as grinding aids in a vertical stirred media mill. The results were assessed in terms of various parameters: product particle size, powder flowability, material coating on the grinding media, and energy consumption. Remarkably, the study showed that the use of any of the grinding aids tested enhanced the grinding process in comparison with the no-aid condition. The best product fineness value was achieved with pomace oil followed by the by-product glycerin, among the grinding aids tested in both samples. Moreover, a higher media coating reduction and the highest energy saving were achieved with pomace oil. The most significant and lowest increase in the fluidity index was achieved with pomace oil and paper wastewater, respectively. Additionally, the Fourier transform infrared spectroscopy (FTIR) performed to reveal the interaction between particle surfaces and grinding aids demonstrated the activity of pomace oil and glycerin polar functional groups on particle surfaces. The analysis of the agglomeration phenomenon with SEM (scanning electron microscopy) micrographs showed that particle agglomeration could be eliminated with the pomace oil. Thermogravimetric analysis (TGA) was used to investigate changes in the mass of the samples' due to temperature changes. With this study, a significant contribution will be made to the ecosystem using waste marble powder whose storage problematic.