Fast Energy Storage of SnS2 Anode Nanoconfined in Hollow Porous Carbon Nanofibers for Lithium‐Ion Batteries

Abstract The development of conversion‐typed anodes with ultrafast charging and large energy storage is quite challenging due to the sluggish ions/electrons transfer kinetics in bulk materials and fracture of the active materials. Herein, the design of porous carbon nanofibers/SnS 2 composite (SnS 2 @N‐HPCNFs) for high‐rate energy storage, where the ultrathin SnS 2 nanosheets are nanoconfined in N‐doped carbon nanofibers with tunable void spaces, is reported. The highly interconnected carbon nanofibers in three‐dimensional (3D) architecture provide a fast electron transfer pathway and alleviate the volume expansion of SnS 2 , while their hierarchical porous structure facilitates rapid ion diffusion. Specifically, the anode delivers a remarkable specific capacity of 1935.50 mAh g −1 at 0.1 C and excellent rate capability up to 30 C with a specific capacity of 289.60 mAh g −1 . Meanwhile, at a high rate of 20 C, the electrode displays a high capacity retention of 84% after 3000 cycles and a long cycle life of 10 000 cycles. This work provides a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast‐charging energy storage devices.