Upgraded β-cyclodextrin-based broad-spectrum adsorbents with enhanced antibacterial property for high-efficient dyeing wastewater remediation

The dyeing wastewater contains amounts of refractory organic compounds, and severely endangers the ecosystem and human health. To alleviate this problem, in this study, the low-cost broad-spectrum nano-adsorbent (denoted as CD/CA-g-CS) with strong antibacterial activity has been synthesized by chemical binding of β-cyclodextrin (β-CD) with chitosan (CS) and citric acid (CA) for high-efficient dyes scavenger. Taking advantage of the extraordinary water insolubility, porous nature and abundant surface groups, the synthesized CD/CA-g-CS outperforms the previously reported adsorbents in terms of adsorption performance. The CD/CA-g-CS exhibits ultrahigh adsorption capacities of 801.66, 770.50 and 946.66 mg/g, respectively mg/g for the cationic dyes of malachite green (MG), basic red (BR) and methylene blue (MB), respectively, while 389.64, 619.60 and 429.22 mg/g for the anionic dyes of acid blue (AB), acid red (AR) and acid yellow (AY), respectively. The chemical monolayer absorption is further demonstrated by the analysis based on the pseudo-second-order adsorption kinetics and Langmuir isotherm models. The regenerable CD/CA-g-CS not only performs well in one-step removal of the mixed dyes in the simulated sewage, but also exhibits superior performance in purifying real industrial wastewater. Moreover, CD/CA-g-CS endowed with antibacterial activity leads to an inhibition rate of over 99.99% for E. coli. The newly developed CD/CA-g-CS adsorbents are highly promising for high-efficient dyeing wastewater remediation.