Effective Reinforcement of Visible Light Photocatalytic and Gas Sensing Characteristics of Nanocrystalline TiO2: Gd-Based Nb and Mo Dopants

光催化 材料科学 掺杂剂 锐钛矿 催化作用 共沉淀 纳米晶材料 可见光谱 吸收(声学) 化学工程 分析化学(期刊) 核化学 纳米技术 兴奋剂 光电子学 有机化学 复合材料 化学 工程类
作者
Ghayah M. Alsulaim
出处
期刊:Molecules [Multidisciplinary Digital Publishing Institute]
卷期号:28 (21): 7239-7239 被引量:1
标识
DOI:10.3390/molecules28217239
摘要

Efficient compositions for the selective detection of ethanol gas and the removal of organic contaminants were realized by codoping of (Gd, Nb) and (Gd, Mo) ions into TiO2. TiO2, Ti0.96Gd0.01Nb0.03O2, and Ti0.96Gd0.01Mo0.03O2 samples were prepared by a coprecipitation method. For all compositions, a crystalline anatase phase of TiO2 was detected. Compared to pure TiO2, the absorption edges of Ti0.96Gd0.01Nb0.03O2 and Ti0.96Gd0.01Mo0.03O2 samples were red-shifted, further broadening towards visible light. The morphological studies demonstrate that the grains of TiO2 were more refined after (Gd, Nb) and (Gd, Mo) codoping. The photocatalytic efficiency of the Ti0.96Gd0.01Mo0.03O2 catalyst for degrading 20 mg/L reactive yellow 145, brilliant green, and amoxicillin was 98, 95, and 93% in 90 min, respectively. The reusability experiments indicate that the Ti0.96Gd0.01Mo0.03O2 catalyst had high stability during reuse. The high photocatalytic activity of the Ti0.96Gd0.01Mo0.03O2 catalyst was correlated to the broad visible-light absorption and effective separation of electron–hole pairs by Gd3+ and Mo6+ cations. The gas sensing characteristic is reflected by the high sensitivity of the Ti0.96Gd0.01Nb0.03O2 sensor to ethanol gas in the presence of different gases at 275 °C. The obtained results indicated that the (Gd, Mo) mixture could more effectively induce the photocatalytic properties of TiO2 while (Gd, Nb) dopants were the best for reinforcing its sensing characteristics.

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