余辉
猝灭(荧光)
钙钛矿(结构)
磷光
掺杂剂
激子
材料科学
兴奋剂
光致发光
化学
光电子学
凝聚态物理
结晶学
物理
荧光
光学
伽马射线暴
天文
作者
Zhe Tang,Runze Liu,Junsheng Chen,Daoyuan Zheng,Panwang Zhou,Siping Liu,Tianxin Bai,Kaibo Zheng,Keli Han,Bin Yang
标识
DOI:10.1002/anie.202210975
摘要
Triplet exciton-based long-lived phosphorescence is severely limited by the thermal quenching at high temperature. Herein, we propose a novel strategy based on the energy transfer from triplet self-trapped excitons to Mn2+ dopants in solution-processed perovskite CsCdCl3 . It is found the Mn2+ doped hexagonal phase CsCdCl3 could simultaneously exhibit high emission efficiency (81.5 %) and long afterglow duration time (150 s). Besides, the afterglow emission exhibits anti-thermal quenching from 300 to 400 K. In-depth charge-carrier dynamics studies and density functional theory (DFT) calculation provide unambiguous evidence that carrier detrapping from trap states (mainly induced by Cl vacancy) to localized emission centers ([MnCl6 ]4- ) is responsible for the afterglow emission with anti-thermal quenching. Enlightened by the present results, we demonstrate the application of the developed materials for optical storage and logic operation applications.
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