As the precursor of MXenes (2D transition metal carbides, carbon nitrides and nitrides), MAX phase materials have attracted ever-increasing attention in electrochemical applications. In this work, we have successfully hybridized a MAX phase, Ti2SnC, with various ratios of carbon nanofibers (CNFs) via electrospinning. The results show that the Ti2SnC/CNFs compounds possess a stable lithium ion storage ability as an anode material, reaching a stable specific capacity of up to 367.5 mAh·g−1 after 500 charge/discharge cycles at the current density of 1.0 A g−1, which are drastically better than some other MAX phase materials such as Ti3SiC2 and Nb2SnC. This strategy provides a new pathway for the improvement of the electrochemical stability of MAX phase, which has a wide application prospect.