过电位
磷化物
材料科学
石墨烯
析氧
无定形固体
氧气
化学工程
阴极
催化作用
冶金
纳米技术
化学
金属
电化学
电极
物理化学
有机化学
生物化学
工程类
作者
Quynh Phuong Ngo,Thanh Tuan Nguyen,Manjinder Singh,Ravichandran Balaji,Nam Hoon Kim,Joong Hee Lee
标识
DOI:10.1016/j.apcatb.2023.122674
摘要
The zinc air batteries (ZABs) are emerging as potential energy storage devices, because of its low-cost, safety, and high energy density. The oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) mainly occur at the air-cathode, which play the key role in the ZAB's performance. However, the sluggish oxygen reactions require an overpotential and multiple electron transfer steps. Herein, the unique crystalline/amorphous nanostructure of V-doped Fe2P/FePOx @PG hybrid has been prepared, which showed the electronic structure tuning and synergistic effect. The catalyst exhibited a small overpotential of 270 mV at 10 mA cm−2 for OER, and a high half-wave potential of 0.84 V for ORR. When serving as air-cathode for ZABs, it showed ultralong durability of 600 h with high peak power density of 137 mW cm−2. The solid-state ZABs demonstrated superior performance with different testing conditions, offering high potential to apply to the next generation flexible energy storage devices.
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