材料科学
格子(音乐)
氧气
氢
化学工程
水准点(测量)
无机化学
化学
有机化学
大地测量学
工程类
物理
声学
地理
作者
Xiaojing Liu,Shuaichong Wei,Shuyi Cao,Yongguang Zhang,Wei Xue,Yanji Wang,Guihua Liu,Jingde Li
标识
DOI:10.1002/adma.202405970
摘要
Abstract Earth‐abundant metal oxides are usually considered as stable but catalytically inert toward hydrogen evolution reaction (HER) due to their unfavorable hydrogen intermediate adsorption performance. Herein, a heavy rare earth (Y) and transition metal (Co) dual‐doping induced lattice strain and oxygen vacancy stabilization strategy is proposed to boost CeO 2 toward robust alkaline HER. The induced lattice compression and increased oxygen vacancy (O v ) concentration in CeO 2 synergistically improve the water dissociation on O v sites and sequential hydrogen adsorption at activated O v ‐neighboring sites, leading to significantly enhanced HER kinetics. Meanwhile, Y doping offers stabilization effect on O v by its stronger Y─O bonding over Ce─O, which endows the catalyst with excellent stability. The Y,Co‐CeO 2 electrocatalyst exhibits an ultra‐low HER overpotential (27 mV at 10 mA cm −2 ) and Tafel slope (48 mV dec −1 ), outperforming the benchmark Pt electrocatalyst. Moreover, the anion exchange membrane water electrolyzer incorporated with Y,Co‐CeO 2 achieves excellent stability of 500 h under 600 mA cm −2 . This synergistic lattice strain and oxygen vacancy stabilization strategy sheds new light on the rational development of efficient and stable oxide‐based HER electrocatalysts.
科研通智能强力驱动
Strongly Powered by AbleSci AI