The giant Baerzhe rare-earth-element–Nb–Zr–Be deposit, Inner Mongolia, China, an Early Cretaceous analogue of the Strange Lake rare-metal deposit, Quebec

假象 地质学 锆石 地球化学 独居石 矿化(土壤科学) 稀土元素 变质作用 大气降水 矽卡岩 石英 矿物学 稀土 古生物学 流体包裹体 土壤科学 热液循环 土壤水分
作者
Mingqian Wu,Kun‐Feng Qiu,Xi Diao,Jiadong Ma,Hao‐Cheng Yu,Maoguo An,Cheng-Long Zhi,Lukáš Krmíček,Deng Jun
出处
期刊:Geological Society, London, Special Publications [Geological Society of London]
卷期号:551 (1) 被引量:1
标识
DOI:10.1144/sp551-2023-146
摘要

The Baerzhe deposit represents world-class mineralization of rare metals, in particular rare earth elements (REEs) and Nb, and shares mineralogical and geochemical similarities with the Strange Lake deposit in Canada. However, the mechanisms responsible for the rare-metal enrichment at Baerzhe are still under debate. Mineralization at Baerzhe is characterized by multiple stages of dissolution, re-precipitation and enrichment of rare-metal elements, as with the Strange Lake deposit. Zirconium was concentrated during magmatic fractionation of elpidite in a transsolvus agpaitic granite (Stage I), and was redistributed into zircon–quartz pseudomorphs during Na-metasomatism (Stage II). Rare earth elements, Nb and Be occur as a variety of mineral assemblages, mainly as pseudomorphs after complete replacement of unknown precursor minerals that are disseminated through the hematized transsolvus granites and were precipitated in three sequential stages (Stages III–V): Stage III is characterized by the mineralization of hingganite, aeschynite-(Y), columbite-(Fe) and euxenite-group minerals, accompanied by hematite alteration; the following Stage IV is defined mainly by monazite-(Ce) crystallization, and Stage V by the preceding REE minerals being replaced by light REE minerals (i.e. bastnäsite-(Ce) and fluocerite-(Ce)). The formation of various pseudomorphs as replacement for precursor minerals is also a common feature documented at Strange Lake. Our results call for a re-evaluation of the timing and role of meteoric waters at Baerzhe, which were suggested by previous researchers to have entered the ore-forming system prior to the mineralization of zircon. New in situ O isotopic analyses on pseudomorph-hosted mineral pairs and investigation of silicate melt–fluoride melt immiscibility through observations and analyses of melt inclusions could provide further insights into the nature of the Baerzhe system.

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