单斜晶系
锡
硼
结晶学
水热合成
晶体结构
化学
氢键
热液循环
空间组
红外光谱学
X射线晶体学
无机化学
材料科学
分子
衍射
有机化学
物理
地质学
地震学
光学
作者
Sandra Schönegger,Klaus Wurst,Günter Heymann,Andreas Schaur,Andreas Saxer,Dirk Johrendt,Hubert Huppertz
标识
DOI:10.1016/j.jssc.2017.11.004
摘要
In the system Sn-B-O-H, the first tin borate Sn2B3O6(OH) was successfully synthesized by a simple hydrothermal process. The compound crystallizes in the centrosymmetric monoclinic space group P21/n (no. 14) with the lattice parameters a = 443.5(2), b = 1102.5(4), c = 1396.4(5) pm, and β = 95.31(1)° (Z = 4). Structurally, Sn2B3O6(OH) features infinite chains of B3O8 groups connected along the a axis. The Sn2+ cations are arranged in form of layers between the anionic borate chains. Interestingly, Sn2B3O6(OH) is the first example of a hydrothermally synthesized tin borate, in which adjacent anionic borate chains are further connected by O–H···O hydrogen bond interactions into a three-dimensional structure. The characterization of Sn2B3O6(OH) is based on single-crystal X-ray diffraction data, vibrational spectroscopy, DFT calculations, and thermoanalytical investigations.
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