Biodegradable Transparent Substrate Based on Edible Starch–Chitosan Embedded with Nature-Inspired Three-Dimensionally Interconnected Conductive Nanocomposites for Wearable Green Electronics

Electronic waste (E-waste) contain large environmental contaminants such as toxic heavy metals and hazardous chemicals. These contaminants would migrate into drinking water or food chains and pose a serious threat to environment and human health. Biodegradable green electronics has great potential to address the issue of E-waste. Here, we report on a novel biodegradable and flexible transparent electrode, integrating three-dimensionally (3D) interconnected conductive nanocomposites into edible starch–chitosan-based substrates. Starch and chitosan are extracted from abundant and inexpensive potato and crab shells, respectively. Nacre-inspired interface designs are introduced to construct a 3D interconnected single wall carbon nanotube (SCNT)–pristine graphene (PG)-conductive polymer network architecture. The inorganic one-dimensional SCNT and two-dimensional PG sheets are tightly cross-linked together at the junction interface by long organic conductive poly(3,4-ethylenedioxythiophene) (PEDOT) chains. The formation of a 3D continuous SCNT–PG–PEDOT conductive network leads to not only a low sheet resistance but also a superior flexibility. The flexible transparent electrode possesses an excellent optoelectronic performance: typically, a sheet resistance of 46 Ω/sq with a transmittance of 83.5% at a typical wavelength of 550 nm. The sheet resistance of the electrode slightly increased less than 3% even after hundreds of bending cycles. The lightweight flexible and biocompatible transparent electrode could conform to skin topography or any other arbitrary surface naturally. The edible starch–chitosan substrate-based transparent electrodes could be biodegraded in lysozyme solution rapidly at room temperature without producing any toxic residues. SCNT–PG–PEDOT can be recycled via a membrane process for further fabrication of conductive and reinforcement composites. This high-performance biodegradable transparent electrode is a promising material for next-generation wearable green optoelectronics, transient electronics, and edible electronics.