材料科学
双极扩散
聚合物
噻吩
接受者
共轭体系
循环伏安法
缩聚物
电子迁移率
高分子化学
分析化学(期刊)
化学
光电子学
电化学
有机化学
物理化学
电子
电极
凝聚态物理
复合材料
物理
量子力学
作者
Yu Jiang,Yao Gao,Hongkun Tian,Junqiao Ding,Donghang Yan,Yanhou Geng,Fosong Wang
出处
期刊:Macromolecules
[American Chemical Society]
日期:2016-03-10
卷期号:49 (6): 2135-2144
被引量:65
标识
DOI:10.1021/acs.macromol.6b00004
摘要
Four donor (D)–acceptor (A) conjugated polymers with isoindigo[7,6-g]isoindigo ([3E,8E]-3,8-bis(2-oxoindolin-3-ylidene)-6,8-dihydroindolo[7,6-g]indole-2,7(1H,3H)-dione, DIID) as A-unit and thiophene derivatives as D-units were synthesized by Stille polycondensation. Optical and electrochemical properties of the polymers were studied by UV–vis–NIR absorption spectrometer and cyclic voltammetry. Compared with isoindigo-based analogues, the polymers display much broader absorption spectra (covering 400–950 nm) and remarkably lower bandgaps (ca. 1.3 eV). All polymers showed ambipolar transport properties as evaluated by bottom-gate/top-contact (BGTC) and top-gate/bottom-contact (TGBC) organic thin film transistors (OTFTs) in air. Gate-voltage-dependent hole mobility (μh) was observed for BGTC devices, while the mobility of TGBC devices exhibited weak gate-voltage dependence. P3 delivered the best device performance. At the optimized thermal annealing temperature (200 °C), a μh of 1.79 cm2/(V s) and an electron mobility (μe) of 0.087 cm2/(V s) were demonstrated with BGTC devices, and μh calculated from the higher VGS region is decreased to 0.35 cm2/(V s). The relatively balanced hole and electron mobilities were observed for TGBC devices based on P3, which were 0.45 and 0.16 cm2/(V s), respectively.
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