纳米团簇
纳米反应器
纳米技术
材料科学
表征(材料科学)
纳米颗粒
超分子化学
催化作用
纳米
金属有机骨架
多孔性
金属
纳米尺度
吸附
化学
结晶学
物理化学
晶体结构
冶金
复合材料
生物化学
作者
Donatella Armentano,Emilio Pardo
出处
期刊:The Royal Society of Chemistry eBooks
[The Royal Society of Chemistry]
日期:2021-08-25
卷期号:: 428-461
标识
DOI:10.1039/9781788019705-00428
摘要
Herein, experimental developments in the construction of various well defined small aggregations of metal atoms, close to or within the sub-nanometric regime, so-called metal nanoclusters (MNCs), are summarized. In particular, the discussion is focussed on the use of metal–organic frameworks (MOFs) – an emerging type of porous functional materials capable of acting as vessels or as chemical nanoreactors to template the growth of atomically precise nanoclusters – for application in heterogeneous catalysts, with a particular focus on how the MOFs surface engineering, morphology control, composition manipulation and support effect can tune their nuclearity/size and catalytic performance. Compared to regular nanoparticles, which are somewhat polydisperse, atomically precise nanoclusters are molecularly pure, ultra small nanoparticles (from sub-nanometre to 2 nm) and exhibit strong quantum confinement effects due to ultra small sizes. We will show that, despite the increasing number of reports on MNCs, their crystallographic characterization is still highly challenging. Indeed, cases of crystallographically solved atomic structures – which are of critical importance in order to shed light on supramolecular host–guest interactions – are still scarce. Structural awareness is mandatory to further enhance the efficiency of current heterogeneous catalysts and pave the way for future design of more advanced catalysts with mechanistic understanding of catalytic reactions, especially at the atomic scale.
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