羰基化
对映选择合成
钯
催化作用
化学
组合化学
铑
有机化学
一氧化碳
作者
Jin‐Bao Peng,Xin‐Lian Liu,Jian Lin,Xiao‐Feng Wu
标识
DOI:10.1007/s11426-021-1165-6
摘要
Abstract Carbonylation, one of the most powerful approaches to the preparation of carbonylated compounds, has received significant attention from researchers active in various fields. Indeed, impressive progress has been made on this subject over the past few decades. Among the various types of carbonylation reactions, asymmetric carbonylation is a straightforward methodology for constructing chiral compounds. Although rhodium-catalyzed enantioselective hydroformylations have been discussed in several elegant reviews, a general review on palladium-catalyzed asymmetric carbonylations is still missing. In this review, we summarize and discuss recent achievements in palladium-catalyzed asymmetric carbonylation reactions. Notably, this review’s contents are categorized by reaction type.
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